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CAS 2923-28-6
O−SOOFFFAg⁺
CAgF3O3S256.93 g/mol
2D structure

Silver trifluoromethanesulfonate

Silver triflate

Silver trifluoromethanesulfonate (silver triflate) is the triflate salt of Ag+. It is a colorless or white solid that is soluble in water and organic solvents including benzene.

CAS No.
2923-28-6
Molecular formula
CAgF3O3S
Molecular weight
256.93 g/mol
Purity
On request

Appearancelight beige crystalline powder

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Made in our own plantsPanoli GIDC, Ankleshwar

Tested in our QC labHPLC · GC · KF and more

COA & SDSShared with every quotation

Grams to multi-tonnesSamples to commercial supply

Overview

It is a source of a weakly coordinating anion, used as a halide abstraction reagent and as a soluble source of silver ions.

Applications

  • Preparation of organic and inorganic triflates
  • Halide abstraction
  • Generation of electrophilic onium species
  • Promoting Friedel-Crafts reactions, nucleophilic alkene cyclization and esterification
  • Producing olefins from secondary phosphates and thiophosphates
  • Etherification of alcohols with primary alkyl halides under mild conditions

Technical specifications

Boiling point162ºC at 760mmHg
Melting Point356-357ºC
Vapor Pressure1.14mmHg at 25°C
StabilityStable, but may be light sensitive. Incompatible with strong acids, strong oxidizing agents.

Packaging & storage

Storage

2-8°C

Safety information

  • H315: Causes skin irritation.
  • H318: Causes serious eye damage.

Full details are in the Safety Data Sheet, sent with every quotation.

Also known as

Trifluoromethanesulfonic Acid Silver SaltSilver(I) TriflateSilver TrifluoromethanesulphonateSilver TrifluoromethanesulfonateAg(Otf),silver,trifluoromethyl)sulfonateSilver(I) Trifluoromethanesulfonate