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CAS 464-05-1
NH+O−OFFF
C7H6F3NO2193.12 g/mol
2D structure

Pyridinium trifluoroacetate

Pyridine trifluoroacetate, pyridine.CF3CO2H, pyridine*TFA, Pyridinium trifluoroacetate, Trifluoroacetic acid pyridine salt, [PyH]CF3CO2, PTFA, pyridine, 2,2,2-trifluoroacetic acid, Pyridine trifluoroacetate salt

CAS No.
464-05-1
Molecular formula
C7H6F3NO2
Molecular weight
193.12 g/mol
Purity
On request

AppearanceWhite crystalline powder

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Grams to multi-tonnesSamples to commercial supply

Overview

Pyridinium TrifluoroacetateThe Cornforth Reagent, also known as pyridinium dichromate (PDC) is dichromate's pyridinium-based salt which has the formula of [C5H5NH]2[Cr2O7. The compound's name is derived from the British-Australian chemist Sir John Warcup Cornforth (b. 1917) who first introduced it in the year 1962.

The Cornforth Reagent is an oxidizing agent that converts both secondary and primary alcohols into ketones and aldehydes, and ketones, respectively. In terms of chemical structure and properties, it is closely linked to other compounds derived from Hexavalent chromium Oxides, such as pyridinium chlorochromate, and Collins reagent. Due to their toxic nature, the reagents aren't widely employed in modern times.

Technical specifications

Molecular weight193.12300
Boiling point72.2ºC at 760 mmHg
Flash Point102.7ºC
Vapor Pressure96.2mmHg at 25°C

Safety information

  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation
  • H335: May cause respiratory irritation

Full details are in the Safety Data Sheet, sent with every quotation.

Also known as

pyridine.CF3CO2HTrifluoroacetic acid pyridine saltPTFA